Publications of Bruce S. Brunschwig

1.     Nunez, P. D.; Richter, M. H.; Roske, C. W.; Piercy, B.; Losego, M.; Kozeny, S. J.; Fermin, D. J.; Hu, S.; Brunschwig, B. S.; Lewis, N. S. “Characterization of Electronic Transport through Amorphous TiO2 Produced by Atomic-Layer Deposition.” J. Phys. Chem. C 2019, Submitted.

2.     Sun, K.; Ritzert, N. L.; John, J.; Tan, H.; Hale, W. G.; Jiang, J.; Moreno-Hernandez, I.; Papadantonakis, K. M.; Moffat, T. P.; Brunschwig, B. S.; et al. “Performance and Failure Modes of Si Anodes Patterned with Thin-Film Ni Catalyst Islands for Water Oxidation.” Sustainable Energy & Fuels 2018, 2 (5), 983–998; https://doi.org/10.1039/C7SE00583K.

3.     Moreno-Hernandez, I. A.; Brunschwig, B. S.; Lewis, N. S. “Tin Oxide as a Protective Heterojunction with Silicon for Efficient Photoelectrochemical Water Oxidation in Strongly Acidic or Alkaline Electrolytes.” Adv. Energy Mater. 2018, 8 (24), 1801155; https://doi.org/10.1002/aenm.201801155.

4.     Francis, S. A.; Velazquez, J. M.; Ferrer, I. M.; Torelli, D. A.; Guevarra, D.; McDowell, M. T.; Sun, K.; Zhou, X.; Saadi, F. H.; John, J.; et al. “Reduction of Aqueous CO2 to 1-Propanol at MoS2 Electrodes.” Chem. Mat. 2018, 30 (15), 4902–4908; https://doi.org/10.1021/acs.chemmater.7b04428.

5.     Al-Yasari, A.; Spence, P.; El Moll, H.; Van Steerteghem, N.; Horton, P. N.; Brunschwig, B. S.; Clays, K.; Fielden, J. “Fine-Tuning Polyoxometalate Non-Linear Optical Chromophores: A Molecular Electronic ‘Goldilocks’ Effect.” Dalton Trans. 2018, 47 (31), 10415–10419; https://doi.org/10.1039/c8dt01491d.

6.     Wiensch, J. D.; John, J.; Velazquez, J. M.; Torelli, D. A.; Pieterick, A. P.; McDowell, M. T.; Sun, K.; Zhao, X.; Brunschwig, B. S.; Lewis, N. S. “Comparative Study in Acidic and Alkaline Media of the Effects of PH and Crystallinity on the Hydrogen-Evolution Reaction on MoS2 and MoSe2.” ACS Energy Letters 2017, 2 (10), 2234–2238; https://doi.org/10.1021/acsenergylett.7b00700.

7.     Plymale, N. T.; Dasog, M.; Brunschwig, B. S.; Lewis, N. S. “A Mechanistic Study of the Oxidative Reaction of Hydrogen-Terminated Si(111) Surfaces with Liquid Methanol.” J. Phys. Chem. C 2017, 121 (8), 4270–4282; https://doi.org/10.1021/acs.jpcc.6b11555.

8.     Nellist, M. R.; Chen, Y. K.; Mark, A.; Godrich, S.; Stelling, C.; Jiang, J. J.; Poddar, R.; Li, C. Z.; Kumar, R.; Papastavrou, G.; et al. “Atomic Force Microscopy with Nanoelectrode Tips for High Resolution Eectrochemical, Nanoadhesion, and Nanoelectrical Imaging.” Nanotechnology 2017, 28 (9), 095711; https://doi.org/10.1088/1361-6528/aa5839.

9.     Moreno-Hernandez, I. A.; MacFarland, C. A.; Read, C. G.; Papadantonakis, K. M.; Brunschwig, B. S.; Lewis, N. S. “Crystalline Nickel Manganese Antimonate as a Stable Water-OOxidation Catalyst in Aqueous 1.0 M H2 SO4.” Energy & Environmental Science 2017, 10 (10), 2103–2108; https://doi.org/10.1039/C7EE01486D.

10.  Matheu, R.; Moreno-Hernandez, I. A.; Sala, X.; Gray, H. B.; Brunschwig, B. S.; Llobet, A.; Lewis, N. S. “Photoelectrochemical Behavior of a Molecular Ru-Based Water-Oxidation Catalyst Bound to TiO2 -Protected Si Photoanodes.” J. Am. Chem. Soc. 2017, 139 (33), 11345–11348; https://doi.org/10.1021/jacs.7b06800.

11.  Lichterman, M. F.; Richter, M. H.; Brunschwig, B. S.; Lewis, N. S.; Lewerenz, H. J. “Operando X-Ray Photoelectron Spectroscopic Investigations of the EElectrochemical Double Layer at Ir/KOH(Aq) Z Interfaces.” J. Electron Spectrosc. Relat. Phenom. 2017, 221, 99–105; https://doi.org/10.1016/j.elspec.2017.03.011.

12.  Jiang, J.; Huang, Z.; Xiang, C.; Poddar, R.; Lewerenz, H.-J.; Papadantonakis, K. M.; Lewis, N. S.; Brunschwig, B. S. “Nanoelectrical and Nanoelectrochemical Imaging of Pt/p-Si and Pt/p+ -Si Electrodes.” ChemSusChem 2017, 10 (22), 4657–4663; https://doi.org/10.1002/cssc.201700893.

13.  Buckley, L. E. R.; Coe, B. J.; Rusanova, D.; Joshi, V. D.; Sanchez, S.; Jirasek, M.; Vavra, J.; Khobragade, D.; Severa, L.; Cisarova, I.; et al. “Tunable Chiral Second-Order Nonlinear Optical Chromophores Based on Helquat Dications.” J. Phys. Chem. A 2017, 121 (31), 5842–5855; https://doi.org/10.1021/acs.jpca.7b06057.

14.  Buckley, L. E. R.; Coe, B. J.; Rusanova, D.; Sanchez, S.; Jirasek, M.; Joshi, V. D.; Vavra, J.; Khobragade, D.; Pospisil, L.; Ramesova, S.; et al. “Ferrocenyl Helquats: Unusual Chiral Organometallic Nonlinear Optical Chromophores.” Dalton Transactions 2017, 46 (4), 1052–1064; https://doi.org/10.1039/c6dt04347j.

15.  Al-Yasari, A.; Van Steerteghem, N.; Kearns, H.; El Moll, H.; Faulds, K.; Wright, J. A.; Brunschwig, B. S.; Clays, K.; Fielden, J. “Organoimido-Polyoxometalate Nonlinear Optical Chromophores: A Structural, Spectroscopic, and Computational Study.” Inorganic Chemistry 2017, 56 (17), 10181–10194; https://doi.org/10.1021/acs.inorgchem.7b00708.

16.  Zhuangqun Huang, P. D. W., Rakesh Poddar, Chunzeng Li, Andreas Mark,; Michael R. Nellist, Y. C., Jingjing Jiang, Georg Papastavrou, Shannon W. Boettcher,; Chengxiang Xiang, and B. S. B. “PeakForce Scanning Electrochemical Microscopy with Nanoelectrode Probes.” Microscopy Today 2016, 24, 18–24.

17.  Zhou, X.; Liu, R.; Sun, K.; Papadantonakis, K. M.; Brunschwig, B. S.; Lewis, N. S. “570 MV Photovoltage, Stabilized n-Si/CoOx Heterojunction Photoanodes Fabricated Using Atomic Layer Deposition.” Energy & Environmental Science 2016, 9 (3), 892–897; https://doi.org/10.1039/C5EE03655K.

18.  Velazquez, J. M.; John, J.; Esposito, D. V.; Pieterick, A.; Pala, R.; Sun, G.; Zhou, X.; Huang, Z.; Ardo, S.; Soriaga, M. P.; et al. “A Scanning Probe Investigation of the Role of Surface Motifs in the Vehavior of P-WSe2 Photocathodes.” Energy Environ. Sci. 2016, 9 (1), 164–175; https://doi.org/10.1039/C5EE02530C.

19.  Torelli, D. A.; Francis, S. A.; Crompton, J. C.; Javier, A.; Thompson, J. R.; Brunschwig, B. S.; Soriaga, M. P.; Lewis, N. S. “Nickel-Gallium-Catalyzed Electrochemical Reduction of CO2 to Highly Reduced Products at Low Overpotentials.” ACS Catalysis 2016, 6 (3), 2100–2104; https://doi.org/10.1021/acscatal.5b02888.

20.  Plymale, N. T.; Ramachandran, A. A.; Lim, A.; Brunschwig, B. S.; Lewis, N. S. “Control of the Band-Edge Positions of Crystalline Si(111) by Surface Functionalization with 3,4,5-Trifluorophenylacetylenyl Moieties.” J. Phys. Chem. C 2016, 120 (26), 14157–14169; https://doi.org/10.1021/acs.jpcc.6b03824.

21.  Lichterman, M. F.; Richter, M. H.; Hu, S.; Crumlin, E. J.; Axnanda, S.; Favaro, M.; Drisdell, W.; Hussain, Z.; Brunschwig, B. S.; Lewis, N. S.; et al. “An Electrochemical, Microtopographical and Ambient Pressure X-Ray Photoelectron Spectroscopic Investigation of Si/TiO2 /Ni/Electrolyte Interfaces.” Journal of the Electrochemical Society 2016, 163 (2), H139–H146; https://doi.org/10.1149/2.0861602jes.

22.  Lichterman, M. F.; Sun, K.; Hu, S.; Zhou, X. H.; McDowell, M. T.; Shaner, M. R.; Richter, M. H.; Crumlin, E. J.; Carim, A. I.; Saadi, F. H.; et al. “Protection of Inorganic Semiconductors for Sustained, Efficient Photoelectrochemical Water Oxidation.” Catal Today 2016, 262, 11–23; https://doi.org/10.1016/j.cattod.2015.08.017.

23.  Lewerenz, H. J.; Lichterman, M. F.; Richter, M. H.; Crumlin, E. J.; Hu, S.; Axnanda, S.; Favaro, M.; Drisdell, W.; Hussain, Z.; Brunschwig, B. S.; et al. “Operando Analyses of Solar Fuels Light Absorbers and Catalysts.” Electrochimica Acta 2016, 211, 711–719; https://doi.org/10.1016/j.electacta.2016.06.006.

24.  Huang, Z.; Wolf, P. D.; Poddar, R.; Li, C.; Mark, A.; Nellist, M. R.; Chen, Y.; Jiang, J.; Papastavrou, G.; Boettcher, S. W.; et al. “PeakForce Scanning Electrochemical Microscopy with Nanoelectrode Probes.” Microscopy Today 2016, 24, 18–24.

25.  Hu, S.; Richter, M. H.; Lichterman, M. F.; Beardslee, J.; Mayer, T.; Brunschwig, B. S.; Lewis, N. S. “Electrical, Photoelectrochemical, and Photoelectron Spectroscopic Investigation of the Interfacial Transport and Energetics of Amorphous TiO2 /Si Heterojunctions.” J. Phys. Chem. C 2016, 120 (6), 3117–3129; https://doi.org/10.1021/acs.jpcc.5b09121.

26.  Gupta, A.; Blakemore, J. D.; Brunschwig, B. S.; Gray, H. B. “Immobilization and Electrochemical Properties of Ruthenium and Iridium Complexes on Carbon Electrodes.” Journal of Physics-Condensed Matter 2016, 28 (9), 094002; https://doi.org/10.1088/0953-8984/28/9/094002.

27.  Coe, B. J.; Rusanova, D.; Joshi, V. D.; Sanchez, S.; Vavra, J.; Khobragade, D.; Severa, L.; Cisarova, I.; Saman, D.; Pohl, R.; et al. “Helquat Dyes: Helicene-like Push-Pull Systems with Large Second-Order Nonlinear Optical Responses.” Journal of Organic Chemistry 2016, 81 (5), 1912–1920; https://doi.org/10.1021/acs.joc.5b02692.

28.  Coe, B. J.; Foxon, S. P.; Pilkington, R. A.; Sanchez, S.; Whittaker, D.; Clays, K.; Van Steerteghem, N.; Brunschwig, B. S. “Rhenium(I) Tricarbonyl Complexes with Peripheral N-Coordination Sites: A Foundation for Heterotrimetallic Nonlinear Optical Chromophores.” Organometallics 2016, 35 (17), 3014–3024; https://doi.org/10.1021/acs.organomet.6b00536.

29.  Zhou, X. H.; Liu, R.; Sun, K.; Friedrich, D.; McDowell, M. T.; Yang, F.; Omelchenko, S. T.; Saadi, F. H.; Nielander, A. C.; Yalamanchili, S.; et al. “Interface Engineering of the Photoelectrochemical Performance of Ni-Oxide-Coated N-Si Photoanodes by Atomic-Layer Deposition of Ultrathin Films of Cobalt Oxide.” Energy & Environmental Science 2015, 8 (9), 2644–2649; https://doi.org/10.1039/c5ee01687h.

30.  Wong, K. T.; Kim, Y. G.; Soriaga, M. P.; Brunschwig, B. S.; Lewis, N. S. “Synthesis and Characterization of Atomically Flat Methyl-Terminated Ge(111) Surfaces.” J. Am. Chem. Soc. 2015, 137 (28), 9006–9014; https://doi.org/10.1021/jacs.5b03339.

31.  Sun, K.; McDowell, M. T.; Nielander, A. C.; Hu, S.; Shaner, M. R.; Yang, F.; Brunschwig, B. S.; Lewis, N. S. “Stable Solar-Driven Water Oxidation to O2(g) by Ni-Oxide-Coated Silicon Photoanodes.” J. Phys. Chem. Lett. 2015, 6 (4), 592–598; https://doi.org/10.1021/jz5026195.

32.  Sun, K.; Saadi, F. H.; Lichterman, M. F.; Hale, W. G.; Wang, H. P.; Zhou, X. H.; Plymale, N. T.; Omelchenko, S. T.; He, J. H.; Papadantonakis, K. M.; et al. “Stable Solar-Driven Oxidation of Water by Semiconducting Photoanodes Protected by Transparent Catalytic Nickel Oxide Films.” Proceedings of the National Academy of Sciences of the United States of America 2015, 112 (12), 3612–3617; https://doi.org/10.1073/pnas.1423034112.

33.  Sun, K.; Kuang, Y. J.; Verlage, E.; Brunschwig, B. S.; Tu, C. W.; Lewis, N. S. “Sputtered NiOx Films for Stabilization of p(+)n-InP Photoanodes for Solar-Driven Water Oxidation.” Advanced Energy Materials 2015, 5 (11); https://doi.org/10.1002/aenm.201402276.

34.  Soriaga, M. P.; Baricuatro, J. H.; Cummins, K. D.; Kim, Y. G.; Saadi, F. H.; Sun, G. F.; McCrory, C. C. L.; McKone, J. R.; Velazquez, J. M.; Ferrer, I. M.; et al. “Electrochemical Surface SScience Twenty Years Later: Expeditions into the Electrocatalysis of Reactions at the Core of Artificial Photosynthesis.” Surface Science 2015, 631, 285–294; https://doi.org/10.1016/j.susc.2014.06.028.

35.  Roske, C. W.; Popczun, E. J.; Seger, B.; Read, C. G.; Pedersen, T.; Hansen, O.; Vesborg, P. C. K.; Brunschwig, B. S.; Schaak, R. E.; Chorkendorff, I.; et al. “Comparison of the Performance of CoP-Coated and Pt-Coated Radial Junction n(+)p-Silicon Microwire-Array Photocathodes for the Sunlight-Driven Reduction of Water to H2 (G).” J. Phys. Chem. Lett. 2015, 6 (9), 1679–1683; https://doi.org/10.1021/acs.jpclett.5b00495.

36.  Richter, M. H.; Lichterman, M. F.; Hu, S.; Crumlin, E. J.; Mayer, T.; Axnanda, S.; Favaro, M.; Drisdell, W.; Hussain, Z.; Brunschwig, B. S.; et al. “Measurement of the Energy-Band Relations of Stabilized Si Photoanodes Using Operando Ambient Pressure X-Ray Photoelectron Spectroscopy.” ECS Transactions 2015, 66 (6), 105–113.

37.  Plymale, N. T.; Kim, Y. G.; Soriaga, M. P.; Brunschwig, B. S.; Lewis, N. S. “Synthesis, Characterization, and Reactivity of Ethynyl- and Propynyl-Terminated Si(111) Surfaces.” J. Phys. Chem. C 2015, 119 (34), 19847–19862; https://doi.org/10.1021/acs.jpcc.5b05028.

38.  O’Leary, L. E.; Strandwitz, N. C.; Roske, C. W.; Pyo, S.; Brunschwig, B. S.; Lewis, N. S. “Use of Mixed CH3-/HC(O)CH2CH2-Si(111) Functionality to Control Interfacial Chemical and Electronic Properties During the Atomic-Layer Deposition of Ultrathin Oxides on Si(111).” J. Phys. Chem. Lett. 2015, 6 (4), 722–726; https://doi.org/10.1021/jz502542a.

39.  McDowell, M. T.; Lichterman, M. F.; Carim, A. I.; Liu, R.; Hu, S.; Brunschwig, B. S.; Lewis, N. S. “The Influence of Structure and Processing on the Behavior of TiO2  Protective Layers for Stabilization of n-Si/TiO2 /Ni Photoanodes for Water Oxidation.” Acs Applied Materials & Interfaces 2015, 7 (28), 15189–15199; https://doi.org/10.1021/acsami.5b00379.

40.  Liu, R.; Han, L. H.; Huang, Z. Q.; Ferrer, I. M.; Smets, A. H. M.; Zeman, M.; Brunschwig, B. S.; Lewis, N. S. “A Low-Temperature Synthesis of Electrochemical Active Pt Nanoparticles and Thin Films by Atomic Layer Deposition on Si(111) and Glassy Carbon Surfaces.” Thin Solid Films 2015, 586, 28–34; https://doi.org/10.1016/j.tsf.2015.04.018.

41.  Lichterman, M. F.; Richter, M. H.; Hu, S.; Crumlin, E. J.; Axnanda, S.; Favaro, M.; Drisdell, W.; Hussain, Z.; Mayer, T.; Brunschwig, B.; et al. “Investigation of the Si/TiO2 /Electrolyte Interface Using Operando Tender X-Ray Photoelectron Spectroscopy.” Electrochemical SocietyTransactions 2015, 66 (6), 97–103; https://doi.org/10.1149/06606.0097ecst.

42.  Lichterman, M. F.; Hu, S.; Richter, M. H.; Crumlin, E. J.; Axnanda, S.; Favaro, M.; Drisdell, W.; Hussain, Z.; Mayer, T.; Brunschwig, B. S.; et al. “Direct Observation of the Energetics at a Semiconductor/Liquid Junction by Operando X-Ray Photoelectron Spectroscopy.” Energy Environ. Sci. 2015, 8 (8), 2409–2416; https://doi.org/10.1039/C5EE01014D.

43.  Coe, B. J.; Foxon, S. P.; Pilkington, R. A.; Sanchez, S.; Whittaker, D.; Clays, K.; Depotter, G.; Brunschwig, B. S. “Nonlinear Optical Chromophores with Two Ferrocenyl, Octamethylferrocenyl, or 4-(Diphenylamino)Phenyl Groups Attached to Rhenium(I) or Zinc(II) Centers.” Organometallics 2015, 34 (9), 1701–1715; https://doi.org/10.1021/acs.organomet.5600193.

44.  Berweger, S.; Weber, J. C.; John, J.; Velazquez, J. M.; Pieterick, A.; Sanford, N. A.; Davydov, A. V.; Brunschwig, B.; Lewis, N. S.; Wallis, T. M.; et al. “Microwave Near-Field Imaging of Two-Dimensional Semiconductors.” Nano Letters 2015, 15 (2), 1122–1127; https://doi.org/10.1021/nl504960u.

45.  Velazquez, J. M.; Saadi, F. H.; Pieterick, A. P.; Spurgeon, J. M.; Soriaga, M. P.; Brunschwig, B. S.; Lewis, N. S. “Synthesis and Hydrogen-Evolution Activity of Tungsten Selenide Thin Films Deposited on Tungsten Foils.” J Electroanal Chem 2014, 716, 45–48; https://doi.org/10.1016/J.Jelechem.2013.11.030.

46.  Santori, E. A.; Strandwitz, N. C.; Grimm, R. L.; Brunschwig, B. S.; Atwater, H. A.; Lewis, N. S. “Operation of Lightly Doped Si Microwires under High-Level Injection Conditions.” Energy & Environmental Science 2014, 7 (7), 2329–2338; https://doi.org/10.1039/c4ee00202d.

47.  Plymale, N. T.; Brunschwig, B. S.; Lewis, N. S. “Synthesis and Characterization of Well-Ordered Methyl-, Ethynyl-, and Propynyl-Terminated Si(111) Surfaces.” Abstracts of Papers of the American Chemical Society 2014, 248.

48.  McKone, J. R.; Marinescu, S. C.; Brunschwig, B. S.; Winkler, J. R.; Gray, H. B. “Earth-Abundant Hydrogen Evolution Electrocatalysts.” Chem Sci 2014, 5 (3), 865–878; https://doi.org/10.1039/C3sc51711j.

49.  McDowell, M. T.; Lichterman, M. F.; Spurgeon, J. M.; Hu, S.; Sharp, I. D.; Brunschwig, B. S.; Lewis, N. S. “Improved Stability of Polycrystalline Bismuth Vanadate Photoanodes by Use of Dual-Layer Thin TiO2 /Ni Coatings.” J. Phys. Chem. C 2014, 118 (34), 19618–19624; https://doi.org/10.1021/jp506133y.

50.  Lichterman, M. F.; Carim, A. I.; McDowell, M. T.; Hu, S.; Gray, H. B.; Brunschwig, B. S.; Lewis, N. S. “Stabilization of N-Cadmium Telluride Photoanodes for Water Oxidation to O2 (g) in Aqueous Alkaline Electrolytes Using Amorphous TiO2  Films Formed by Atomic-Layer Deposition.” Energy & Environmental Science 2014, 7 (10), 3334–3337; https://doi.org/10.1039/c4ee01914h.

51.  Lattimer, J. R. C.; Blakemore, J. D.; Sattler, W.; Gul, S.; Chatterjee, R.; Yachandra, V. K.; Yano, J.; Brunschwig, B. S.; Lewis, N. S.; Gray, H. B. “Assembly, Characterization, and Electrochemical Properties of Immobilized Metal Bipyridyl Complexes on Silicon(111) Surfaces.” Dalton Trans. 2014, 43 (40), 15004–15012; https://doi.org/10.1039/c4dt01149j.

52.  Laga, S. M.; Blakemore, J. D.; Henling, L. M.; Brunschwig, B. S.; Gray, H. B. “Catalysis of Proton Reduction by a BO4-Bridged Dicobalt Glyoxime.” Inorganic Chemistry 2014, 53 (24), 12668–12670; https://doi.org/10.1021/ic501804h.

53.  Huang, Z. Q.; McKone, J. R.; Xiang, C. X.; Grimm, R. L.; Warren, E. L.; Spurgeon, J. M.; Lewerenz, H. J.; Brunschwig, B. S.; Lewis, N. S. “Comparison Between the Measured and Modeled Hydrogen-Evolution Activity of Ni- or Pt-Coated Silicon Photocathodes.” International Journal of Hydrogen Energy 2014, 39 (28), 16220–16226; https://doi.org/10.1016/j.ijhydene.2013.12.162.

54.  Hu, S.; Shaner, M. R.; Beardslee, J. A.; Lichterman, M.; Brunschwig, B. S.; Lewis, N. S. “Amorphous TiO2  Coatings Stabilize Si, GaAs, and GaP Photoanodes for Efficient Water Oxidation.” Science 2014, 344 (6187), 1005–1009.

55.  Coridan, R. H.; Arpin, K. A.; Brunschwig, B. S.; Braun, P. V.; Lewis, N. S. “Photoelectrochemical Behavior of Hierarchically Structured Si/WO3 Core-Shell Tandem Photoanodes.” Nano Letters 2014, 14 (5), 2310–2317.

56.  Coe, B. J.; Helliwell, M.; Peers, M. K.; Raftery, J.; Rusanova, D.; Clays, K.; Depotter, G.; Brunschwig, B. S. “Synthesis, Structures, and Optical Properties of Ruthenium(II) Complexes of the Tris(1-Pyrazolyl)Methane Ligand.” Inorganic Chemistry 2014, 53 (7), 3798–3811; https://doi.org/10.1021/ic500145r.

57.  Blakemore, J. D.; Hernandez, E. S.; Sattler, W.; Hunter, B. M.; Henling, L. M.; Brunschwig, B. S.; Gray, H. B. “Pentamethylcyclopentadienyl Rhodium Complexes.” Polyhedron 2014, 84, 14–18; https://doi.org/10.1016/j.poly.2014.05.022.

58.  Walter, M. G.; Liu, X. L.; O’Leary, L. E.; Brunschwig, B. S.; Lewis, N. S. “Electrical Junction Behavior of Poly(3,4-Ethylenedioxythiophene) (PEDOT) Contacts to H-Terminated and CH3-Terminated p-, n-, and n(+)-Si(111) Surfaces.” J. Phys. Chem. C 2013, 117 (28), 14485–14492; https://doi.org/10.1021/jp4018162.

59.  Reyes-Gil, K. R.; Wiggenhorn, C.; Brunschwig, B. S.; Lewis, N. S. “Comparison between the Quantum Yields of Compact and Porous WO3 Photoanodes.” J. Phys. Chem. C 2013, 117 (29), 14947–14957; https://doi.org/10.1021/Jp4025624.

60.  O’Leary, L. E.; Rose, M. J.; Ding, T. X.; Johansson, E.; Brunschwig, B. S.; Lewis, N. S. “Heck Coupling of Olefins to Mixed Methyl/Thienyl Monolayers on Si(111) Surfaces.” J. Am. Chem. Soc. 2013, 135 (27), 10081–10090; https://doi.org/10.1021/ja402495e.

61.  Mi, Q. X.; Coridan, R. H.; Brunschwig, B. S.; Gray, H. B.; Lewis, N. S. “Photoelectrochemical Oxidation of Anions by WO3 in Aqueous and Nonaqueous Electrolytes.” Energ Environ Sci 2013, 6 (9), 2646–2653; https://doi.org/10.1039/C3ee40712h.

62.  Lichterman, M. F.; Shaner, M. R.; Handler, S. G.; Brunschwig, B. S.; Gray, H. B.; Lewis, N. S.; Spurgeon, J. M. “Enhanced Stability and Activity for Water Oxidation in Alkaline Media with Bismuth Vanadate Photoelectrodes Modified with a Cobalt Oxide Catalytic Layer Produced by Atomic Layer Deposition.” J. Phys. Chem. Lett. 2013, 4 (23), 4188–4191; https://doi.org/10.1021/Jz4022415.

63.  Lattimer, J. R. C.; Brunschwig, B. S.; Lewis, N. S.; Gray, H. B. “Redox Properties of Mixed Methyl/Vinylferrocenyl Monolayers on Si(111) Surfaces.” J Phys Chem C 2013, 117 (51), 27012–27022; https://doi.org/10.1021/Jp409958c.

64.  Gleason-Rohrer, D. C.; Brunschwig, B. S.; Lewis, N. S. “Measurement of the Band Bending and Surface Dipole at Chemically Functionalized Si(111)/Vacuum Interfaces.” J. Phys. Chem. C 2013, 117 (35), 18031–18042; https://doi.org/10.1021/Jp401585s.

65.  Fitch, A.; Strandwitz, N. C.; Brunschwig, B. S.; Lewis, N. S. “A Comparison of the Behavior of Single Crystalline and Nanowire Array ZnO Photoanodes.” J Phys Chem C 2013, 117 (5), 2008–2015; https://doi.org/10.1021/Jp3098457.

66.  Dasgupta, S.; Brunschwig, B. S.; Winkler, J. R.; Gray, H. B. “Solar Fuels Editorial.” Chemical Society Reviews 2013, 42 (6), 2213–2214; https://doi.org/10.1039/c3cs90016a.

67.  Coridan, R. H.; Shaner, M.; Wiggenhorn, C.; Brunschwig, B. S.; Lewis, N. S. “Electrical and Photoelectrochemical Properties of WO3/Si Tandem Photoelectrodes.” J Phys Chem C 2013, 117 (14), 6949–6957; https://doi.org/10.1021/Jp311947x.

68.  Coe, B. J.; Foxon, S. P.; Helliwell, M.; Rusanova, D.; Brunschwig, B. S.; Clays, K.; Depotter, G.; Nyk, M.; Samoc, M.; Wawrzynczyk, D.; et al. “Heptametallic, Octupolar Nonlinear Optical Chromophores with Six Ferrocenyl Substituents.” Chemistry-a European Journal 2013, 19 (21), 6613–6629; https://doi.org/10.1002/chem.201204453.

69.  Blakemore, J. D.; Gupta, A.; Warren, J. J.; Brunschwig, B. S.; Gray, H. B. “Noncovalent Immobilization of Electrocatalysts on Carbon Electrodes for Fuel Production.” J. Am. Chem. Soc. 2013, 135 (49), 18288–18291.

70.  Ardo, S.; Roske, C. W.; Warren, E. L.; Brunschwig, B. S.; Atwater, H. A.; Lewis, N. S. “Demonstration of Artificial Photosynthesis with Peeled Silicon Microrod Arrays.” Abstracts of Papers of the American Chemical Society 2013, 246.

71.  Valdez, C. N.; Dempsey, J. L.; Brunschwig, B. S.; Winkler, J. R.; Gray, H. B. “Catalytic Hydrogen Evolution from a Covalently Linked Dicobaloxime.” Proceedings of the National Academy of Sciences of the United States of America 2012, 109 (39), 15589–15593; https://doi.org/10.1073/pnas.1118329109.

72.  Santori, E. A.; Maiolo, J. R.; Bierman, M. J.; Strandwitz, N. C.; Kelzenberg, M. D.; Brunschwig, B. S.; Atwater, H. A.; Lewis, N. S. “Photoanodic Behavior of Vapor-Lquid-Solid-Grown, Lightly Doped, Crystalline Si Microwire Arrays.” Energ Environ Sci 2012, 5 (5), 6867–6871; https://doi.org/10.1039/C2ee03468a.

73.  Mi, Q. X.; Zhanaidarova, A.; Brunschwig, B. S.; Gray, H. B.; Lewis, N. S. “A Quantitative AAssessment of the Competition between Water and Anion Oxidation at WO3 PPhotoanodes in Acidic Aqueous Eectrolytes.” Energ Environ Sci 2012, 5 (2), 5694–5700; https://doi.org/10.1039/C2ee02929d.

74.  Mi, Q. X.; Ping, Y.; Li, Y.; Cao, B. F.; Brunschwig, B. S.; Khalifah, P. G.; Galli, G. A.; Gray, H. B.; Lewis, N. S. “Thermally Stable N-2-Intercalated WO3 Photoanodes for Water Oxidation.” J. Am. Chem. Soc. 2012, 134 (44), 18318–18324; https://doi.org/10.1021/ja3067622.

75.  Kimball, G. M.; Bosco, J. P.; Mueller, A. M.; Tajdar, S. F.; Brunschwig, B. S.; Atwater, H. A.; Lewis, N. S. “Passivation of Zn3P2 Substrates by Aqueous Chemical Etching and Air Oxidation.” J. Appl. Phys. 2012, 112 (10), 106101.

76.  Huang, Z. Q.; Lin, Y. J.; Xiang, X.; Rodriguez-Cordoba, W.; McDonald, K. J.; Hagen, K. S.; Choi, K. S.; Brunschwig, B. S.; Musaev, D. G.; Hill, C. L.; et al. “In Situ Probe of Photocarrier Dynamics in Water-Splitting Hematite (Alpha-Fe2O3) Electrodes.” Energ Environ Sci 2012, 5 (10), 8923–8926; https://doi.org/10.1039/C2ee22681b.

77.  Grimm, R. L.; Bierman, M. J.; O’Leary, L. E.; Strandwitz, N. C.; Brunschwig, B. S.; Lewis, N. S. “Comparison of the Photoelectrochemical Behavior of H-Terminated and Methyl-Terminated Si(111) Surfaces in Contact with a Series of One-Electron, Outer-Sphere Redox Couples in CH 3 CN.” J. Phys. Chem. C 2012, 116 (44), 23569–23576; https://doi.org/10.1021/jp308461q.

78.  Xiang, C. X.; Kimball, G. M.; Grimm, R. L.; Brunschwig, B. S.; Atwater, H. A.; Lewis, N. S. “820 MV Open-Circuit Voltages from Cu2O/CH3CN Junctions.” Energ Environ Sci 2011, 4 (4), 1311–1318; https://doi.org/10.1039/C0ee00554a.

79.  McKone, J. R.; Warren, E. L.; Bierman, M. J.; Boettcher, S. W.; Brunschwig, B. S.; Lewis, N. S.; Gray, H. B. “Evaluation of Pt, Ni, and Ni-Mo Electrocatalysts for Hydrogen Evolution on Crystalline Si Electrodes.” Energ Environ Sci 2011, 4 (9), 3573–3583; https://doi.org/10.1039/C1ee01488a.

80.  Knapp, D.; Brunschwig, B. S.; Lewis, N. S. “Transmission Infrared Spectra of CH3-, CD3-, and C10H221-Ge(111) Surfaces.” J Phys Chem C 2011, 115 (33), 16389–16397; https://doi.org/10.1021/Jp110550t.

81.  Johansson, E.; Boettcher, S. W.; O’Leary, L. E.; Poletayev, A. D.; Maldonado, S.; Brunschwig, B. S.; Lewis, N. S. “Control of the PH-Dependence of the Band Edges of Si(111) Surfaces Using Mixed Methyl/Allyl Monolayers.” J. Phys. Chem. C 2011, 115 (17), 8594–8601; https://doi.org/10.1021/Jp109799e.

82.  Garcia-Berrios, E.; Gao, T.; Walker, D.; Brunschwig, B. S.; Lewis, N. S. “Composites of Carboxylate-Capped TiO2 Nanoparticles and Carbon Black as Chemiresistive Vapor Sensors.” Sensor Actuat B-Chem 2011, 158 (1), 17–22; https://doi.org/10.1016/J.Snb.2011.04.022.

83.  Garcia-Berrios, E.; Gao, T.; Theriot, J. C.; Woodka, M. D.; Brunschwig, B. S.; Lewis, N. S. “Response and Discrimination Performance of Arrays of Organothiol-Capped Au Nanoparticle Chemiresistive Vapor Sensors.” J Phys Chem C 2011, 115 (14), 6208–6217; https://doi.org/10.1021/Jp110793h.

84.  Dong, Q.; Rose, M. J.; Wong, W.-Y.; Gray, H. B. “Dual Coordination Modes of Ethylene-Linked NP2 Ligands in Cobalt(II) and Nickel(II) Iodides.” Inorganic Chemistry 2011, 50 (20), 10213–10224.

85.  Coe, B. J.; Fielden, J.; Foxon, S. P.; Asselberghs, I.; Clays, K.; Van Cleuvenbergen, S.; Brunschwig, B. S. “Ferrocenyl Diquat Derivatives: Nonlinear Optical Activity, Multiple Redox States, and Unusual Reactivity.” Organometallics 2011, 30 (21), 5731–5743; https://doi.org/10.1021/Om200604f.

86.  Boettcher, S. W.; Warren, E. L.; Putnam, M. C.; Santori, E. A.; Turner-Evans, D.; Kelzenberg, M. D.; Walter, M. G.; McKone, J. R.; Brunschwig, B. S.; Atwater, H. A.; et al. “Photoelectrochemical Hydrogen Evolution Using Si Microwire Arrays.” J. Am. Chem. Soc. 2011, 133 (5), 1216–1219.

87.  Aria, A. I.; Gharib, M. “Reversible Tuning of the Wettability of Carbon Nanotube Arrays: The Effect of Ultraviolet/Ozone and Vacuum Pyrolysis Treatments.” Langmuir 2011, 27 (14), 9005–9011.

88.  Spurgeon, J. M.; Boettcher, S. W.; Kelzenberg, M. D.; Brunschwig, B. S.; Atwater, H. A.; Lewis, N. S. “Flexible, Polymer-Supported, Si Wire Array Photoelectrodes.” Advanced Materials 2010, 22 (30), 3277-+.

89.  O’Leary, L. E.; Johansson, E.; Brunschwig, B. S.; Lewis, N. S. “Synthesis and Characterization of Mixed Methyl/Allyl Monolayers on Si(111) .” The Journal of Physical Chemistry B 2010, 114 (45), 14298–14302; https://doi.org/10.1021/jp911379c.

90.  Knapp, D.; Brunschwig, B. S.; Lewis, N. S. “Chemical, Electronic, and Electrical Properties of Alkylated Ge(111) Surfaces.” J Phys Chem C 2010, 114 (28), 12300–12307; https://doi.org/10.1021/Jp101375x.

91.  Garcia-Berrios, E.; Gao, T.; Woodka, M. D.; Maldonado, S.; Brunschwig, B. S.; Ellsworth, M. W.; Lewis, N. S. “Response versus Chain Length of Alkanethiol-Capped Au Nanoparticle Chemiresistive Chemical Vapor Sensors.” J. Phys. Chem. C 2010, 114 (50), 21914–21920; https://doi.org/10.1021/Jp101331g.

92.  Coe, B. J.; Foxon, S. P.; Harper, E. C.; Helliwell, M.; Raftery, J.; Swanson, C. A.; Brunschwig, B. S.; Clays, K.; Franz, E.; Garin, J.; et al. “Evolution of Linear Absorption and Nonlinear Optical Properties in V-Shaped Ruthenium(II)-Based Chromophores.” Journal of the American Chemical Society 2010, 132 (5), 1706–1723.

93.  Coe, B. J.; Fielden, J.; Foxon, S. P.; Asselberghs, I.; Clays, K.; Brunschwig, B. S. “Two-Dimensional, Pyrazine-Based Nonlinear Optical Chromophores with Ruthenium(II) Ammine Electron Donors.” Inorganic Chemistry 2010, 49 (22), 10718–10726.

94.  Coe, B. J.; Fielden, J.; Foxon, S. P.; Helliwell, M.; Asselberghs, I.; Clays, K.; De Mey, K.; Brunschwig, B. S. “Syntheses and Properties of Two-Dimensional, Dicationic Nonlinear Optical Chromophores Based on Pyrazinyl Cores.” Journal of Organic Chemistry 2010, 75 (24), 8550–8563.

95.  Coe, B. J.; Fielden, J.; Foxon, S. P.; Helliwell, M.; Brunschwig, B. S.; Asselberghs, I.; Clays, K.; Olesiak, J.; Matczyszyn, K.; Samoc, M. “Quadratic and Cubic Nonlinear Optical Properties of Salts of Diquat-Based Chromophores with Diphenylamino Substituents.” J. Phys. Chem. A 2010, 114 (45), 12028–12041.

96.  Coe, B. J.; Fielden, J.; Foxon, S. P.; Harris, J. A.; Helliwell, M.; Brunschwig, B. S.; Asselberghs, I.; Clays, K.; Garin, J.; Orduna, J. “Diquat Derivatives: Highly Active, Two-Dimensional Nonlinear Optical Chromophores with Potential Redox Switchability.” Journal of the American Chemical Society 2010, 132 (30), 10498–10512.

97.  Coe, B. J.; Fielden, J.; Foxon, S. P.; Brunschwig, B. S.; Asselberghs, I.; Clays, K.; Samoc, A.; Samoc, M. “Combining Very Large Quadratic and Cubic Nonlinear Optical Responses in Extended, Tris-Chelate Metallochromophores with Six π-Conjugated Pyridinium Substituents.” Journal of the American Chemical Society 2010, 132 (10), 3496–3513; https://doi.org/10.1021/ja910538s.

98.  Plass, K. E.; Filler, M. A.; Spurgeon, J. M.; Kayes, B. M.; Maldonado, S.; Brunschwig, B. S.; Atwater, H. A.; Lewis, N. S. “Flexible Polymer-Embedded Si Wire Arrays.” Adv Mater 2009, 21 (3), 325–328; https://doi.org/10.1002/Adma.200802006.

99.  Johansson, E.; Hurley, P. T.; Brunschwig, B. S.; Lewis, N. S. “Infrared Vibrational Spectroscopy of Isotopically Labeled Ethyl-Terminated Si(111) Surfaces Prepared Using a Two-Step Chlorination/Alkylation Procedure.” J Phys Chem C 2009, 113 (34), 15239–15245; https://doi.org/10.1021/Jp901792y.

100.     Dempsey, J. L.; Brunschwig, B. S.; Winkler, J. R.; Gray, H. B. “Hydrogen Evolution Catalyzed by Cobaloximes.” Accounts of Chemical Research 2009, 42 (12), 1995–2004.

101.     Coe, B. J.; Foxon, S. P.; Harper, E. C.; Raftery, J.; Shaw, R.; Swanson, C. A.; Asselberghs, I.; Clays, K.; Brunschwig, B. S.; Fitch, A. G. “Nonlinear Optical and Related Properties of Iron(II) Pentacyanide Complexes with Quaternary Nitrogen Electron Acceptor Units.” Inorganic Chemistry 2009, 48 (4), 1370–1379.

102.     Coe, B. J.; Foxon, S. P.; Harper, E. C.; Harris, J. A.; Helliwell, M.; Raftery, J.; Asselberghs, I.; Clays, K.; Franz, E.; Brunschwig, B. S.; et al. “The Syntheses, Structures and Nonlinear Optical and Related Properties of Salts with Julolidinyl Electron Donor Groups.” Dyes Pigments 2009, 82 (2), 171–186; https://doi.org/10.1016/J.Dyepig.2008.12.010.

103.     Coe, B. J.; Docherty, R. J.; Foxon, S. P.; Harper, E. C.; Helliwell, M.; Raftery, J.; Clays, K.; Franz, E.; Brunschwig, B. S. “Syntheses and Properties of Salts of Chromophores with Ferrocenyl Electron Donor Groups and Quaternary Nitrogen Acceptors.” Organometallics 2009, 28 (24), 6880–6892; https://doi.org/10.1021/Om9007955.

104.     Woodka, M. D.; Brunschwig, B. S.; Lewis, N. S. Extraction of Spatiotemporal Response Information from Sorption-Based Cross-Reactive Sensor Arrays for the Identification and Quantification of Analyte Mixtures. In Sensors and Smart Structures Technologies for Civil, Mechanical, and Aerospace Systems 2008, Pts 1 and 2, Tomizuka, M., Ed., Proceedings of the Society of Photo-Optical Instrumentation Engineers (Spie), 2008.

105.     Traub, M. C.; Biteen, J. S.; Michalak, D. J.; Webb, L. J.; Brunschwig, B. S.; Lewis, N. S. “Phosphine Functionalization of GaAs(111)A Surfaces.” J Phys Chem C 2008, 112 (47), 18467–18473; https://doi.org/10.1021/Jp803992h.

106.     Traub, M. C.; Biteen, J. S.; Brunschwig, B. S.; Lewis, N. S. “Passivation of GaAs Nanocrystals by Chemical Functionalization.” Journal of the American Chemical Society 2008, 130 (3), 955–964.

107.     Spurgeon, J. M.; Plass, K. E.; Kayes, B. M.; Brunschwig, B. S.; Atwater, H. A.; Lewis, N. S. “Repeated Epitaxial Growth and Transfer of Arrays of Patterned, Vertically AAligned, Crystalline Si Wires from a Single Si(111) Substrate.” Appl Phys Lett 2008, 93 (3); https://doi.org/10.1063/1.2959184.

108.     Smeigh, A. L.; Katz, J. E.; Brunschwig, B. S.; Lewis, N. S.; McCusker, J. K. “Effect of the Presence of Iodide on the Electron Injection Dynamics of Dye-Sensitized TiO2-Based Solar Cells.” J Phys Chem C 2008, 112 (32), 12065–12068; https://doi.org/10.1021/Jp803402x.

109.     Plass, K. E.; Liu, X.; Brunschwig, B. S.; Lewis, N. S. “Passivation and Secondary Functionalization of Allyl-Terminated Si(111) Surfaces.” Chem Mater 2008, 20 (6), 2228–2233; https://doi.org/10.1021/Cm7024679.

110.     Papadantonakis, K. M.; Brunschwig, B. S.; Lewis, N. S. “Scanning Tunneling Microscopy Studies of Monolayer Templates: Alkylthioethers and Alkylethers.” Langmuir 2008, 24 (19), 10543–10548.

111.     Papadantonakis, K. A.; Brunschwig, B. S.; Lewis, N. S. “Use of Alkane Monolayer Templates to Modify the Structure of Alkyl Ether MMonolayers on Highly Ordered Pyrolytic Graphite.” Langmuir 2008, 24 (3), 857–861.

112.     Maldonado, S.; Knapp, D.; Lewis, N. S. “Near-Ideal Photodiodes from Sintered Gold Nanoparticle Films on Methyl-Terminated Si(111) Surfaces.” J. Am. Chem. Soc. 2008, 130 (11), 3300–3301; https://doi.org/10.1021/ja800603v.

113.     Maldonado, S.; Garcia-Berrios, E.; Woodka, M. D.; Brunschwig, B. S.; Lewis, N. S. “Detection of Organic Vapors and NH3(g) Using Thin-Film Carbon Black-Metallophthalocyanine Composite Chemiresistors.” Sensor Actuat B-Chem 2008, 134 (2), 521–531; https://doi.org/10.1016/J.Snb.2008.05.047.

114.     Kayes, B. M.; Filler, M. A.; Henry, M. D.; Maiolo, J. R.; Kelzenberg, M. D.; Putnam, M. C.; Spurgeon, J. M.; Plass, K. E.; Scherer, A.; Lewis, N. S.; et al. Radial Pn Junction. Wire Array Solar Cells. In 2008 33rd IEEE Photovoltaic Specialists Conference, Vols 1-4, IEEE Photovoltaic Specialists Conference, 2008; https://doi.org/10.1109/PVSC.2008.4922460.

115.     Crabtree, G. W.; Lewis, N. S. Solar Energy Conversion. In Physics of Sustainable Energy - Using Energy Efficiently and Producing It Renewably, Hafemeister, D.; Levi, B. G.; Levine, M. D.; Schwartz, P., Eds., Aip Conference Proceedings, 2008.

116.     Coe, B. J.; Fitzgerald, E. C.; Helliwell, M.; Brunschwig, B. S.; Fitch, A. G.; Harris, J. A.; Coles, S. J.; Horton, P. N.; Hursthouse, M. B. “Syntheses and Properties of Heterobimetallic Ligand-Bridged Ruthenium(II)/Rhenium(I) Complexes and Their Monometallic Congeners.” Organometallics 2008, 27 (12), 2730–2742; https://doi.org/10.1021/Om800105c.

117.     Woodka, M. D.; Brunschwig, B. S.; Lewis, N. S. “Use of Spatiotemporal Response Information from Sorption-Based Sensor Arrays to Identify and Quantify the Composition of Analyte Mixtures.” Langmuir 2007, 23 (26), 13232–13241.

118.     Traub, M. C.; Brunschwig, B. S.; Lewis, N. S. “Relationships between Nonadiabatic Bridged Intramolecular, Electrochemical, and Electrical Electron-Transfer Processes.” Journal of Physical Chemistry B 2007, 111 (24), 6676–6683.

119.     Shinozaki, K.; Hayashi, Y.; Brunschwig, B. S.; Fujita, E. “Characterization of Transient Species and Products in Photochemical Reactions of Re(Dmb)(CO)3 Et with and without CO2.” Res Chem Intermediat 2007, 33 (1–2), 27–36; https://doi.org/10.1163/156856707779160807.

120.     Hu, X.; Brunschwig, B. S.; Peters, J. C. “Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocyclic Glyoxime and Tetraimine Complexes.” Journal of the American Chemical Society 2007, 129 (29), 8988–8998.

121.     Harris, J. A.; Trotter, K.; Brunschwig, B. S. “Interfacial Electron Transfer in Metal Cyanide-Sensitized TiO2 Nanoparticles.” Journal of Physical Chemistry B 2007, 111 (24), 6695–6702.

122.     Brunschwig, B. S.; Creutz, C. “Norman Sutin: Contributions to Chemistry.” Journal of Physical Chemistry B 2007, 111 (24), 6593-+.

123.     Webb, L. J.; Michalak, D. J.; Biteen, J. S.; Brunschwig, B. S.; Chan, A. S. Y.; Knapp, D. W.; Meyer, H. M., III; Nemanick, E. J.; Traub, M. C.; Lewis, N. S. “High-Resolution Soft X-Ray Photoelectron Spectroscopic Studies and Scanning Auger Microscopy Studies of the Air Oxidation of Alkylated Silicon(111) Surfaces.” Journal of Physical Chemistry B 2006, 110 (46), 23450–23459.

124.     Walker, D.; Chappel, S.; Mahammed, A.; Brunschwig, B. S.; Winkler, J. R.; Gray, H. B.; Zaban, A.; Gross, Z. “Corrole-Sensitized TiO2 Solar Cells.” J Porphyr Phthalocya 2006, 10 (11), 1259–1262.

125.     Traub, M. C.; Biteen, J. S.; Michalak, D. J.; Webb, L. J.; Brunschwig, B. S.; Lewis, N. S. “High-Resolution X-Ray Photoelectron Spectroscopy of Chlorine-Terminated GaAs(111)A Surfaces.” JOURNAL OF PHYSICAL CHEMISTRY B 2006, 110 (32), 15641–15644; https://doi.org/10.1021/jp061623n.

126.     Royea, W. J.; Hamann, T. W.; Brunschwig, B. S.; Lewis, N. S. “A Comparison between Interfacial Electron-Transfer Rate Constants at Metallic and Graphite Electrodes.” JOURNAL OF PHYSICAL CHEMISTRY B 2006, 110 (39), 19433–19442; https://doi.org/10.1021/jp062141e.

127.     Nemanick, E. J.; Hurley, P. T.; Webb, L. J.; Knapp, D. W.; Michalak, D. J.; Brunschwig, B. S.; Lewis, N. S. “Chemical and Electrical Passivation of Single-Crystal Silicon(100) Surfaces through a Two-Step Chlorination/Alkylation Process.” Journal of Physical Chemistry B 2006, 110 (30), 14770–14778.

128.     Nemanick, E. J.; Hurley, P. T.; Brunschwig, B. S.; Lewis, N. S. “Chemical and Electrical Passivation of Silicon (111) Surfaces through Functionalization with Sterically Hindered Alkyl Groups.” Journal of Physical Chemistry B 2006, 110 (30), 14800–14808.

129.     Hurley, P. T.; Nemanick, E. J.; Brunschwig, B. S.; Lewis, N. S. “Covalent Attachment of Acetylene and Methylacetylene Functionality to Si(111) Surfaces: Scaffolds for Organic Surface Functionalization While Retaining Si-C Passivation of Si(111) Surface Sites.” Journal of the American Chemical Society 2006, 128 (31), 9990–9991.

130.     Hamann, T. W.; Gstrein, F.; Brunschwig, B. S.; Lewis, N. S. “Measurement of the Driving Force Dependence of Interfacial Charge-Transfer Rate Constants in Response to PH Changes at n-ZnO/H2O Interfaces.” Chem Phys 2006, 326 (1), 15–23; https://doi.org/10.1016/J.Chemphys.2006.02.027.

131.     Hamann, T. W.; Brunschwig, B. S.; Lewis, N. S. “Comparison of the Self-Exchange and Interfacial Charge-Transfer Rate Constants for Methyl- versus Tert-Butyl-Substituted Os(III) Polypyridyl Complexes.” JOURNAL OF PHYSICAL CHEMISTRY B 2006, 110 (50), 25514–25520; https://doi.org/10.1021/jp0649697.

132.     Gao, T.; Woodka, M. D.; Brunschwig, B. S.; Lewis, N. S. “Chemiresistors for Array-Based Vapor Sensing Using Composites of Carbon Black with Low Volatility Organic Molecules.” CHEMISTRY OF MATERIALS 2006, 18 (22), 5193–5202; https://doi.org/10.1021/cm060905x.

133.     Fujita, E.; Brunschwig, B. S.; Creutz, C.; Muckerman, J. T.; Sutin, N.; Szalda, D.; van Eldik, R. “Transition State Characterization for the Reversible Binding of Dihydrogen to Bis(2,2’-Bipyridine)Rhodium(I) from Temperature- and Pressure-Dependent Experimental and Theoretical Studies.” Inorganic Chemistry 2006, 45 (4), 1595–1603.

134.     Creutz, C.; Brunschwig, B. S.; Sutin, N. “Interfacial Charge-Transfer Absorption: 3. Application to Semiconductor-Molecule Assemblies.” JOURNAL OF PHYSICAL CHEMISTRY B 2006, 110 (50), 25181–25190; https://doi.org/10.1021/jp063953d.

135.     Creutz, C.; Brunschwig, B. S.; Sutin, N. “Interfacial Charge Transfer Absorption: Application to Metal–Molecule Assemblies.” Chem Phys 2006, 324 (1), 244–258; https://doi.org/10.1016/J.Chemphys.2005.12.015.

136.     Coe, B. J.; Harris, J. A.; Hall, J. J.; Brunschwig, B. S.; Hung, S.-T.; Libaers, W.; Clays, K.; Coles, S. J.; Horton, P. N.; Light, M. E.; et al. “Syntheses and Quadratic Nonlinear Optical Properties of Salts Containing Benzothiazolium Electron-Acceptor Groups.” CHEMISTRY OF MATERIALS 2006, 18 (25), 5907–5918; https://doi.org/10.1021/cm061594t.

137.     Coe, B. J.; Harries, J. L.; Helliwell, M.; Jones, L. A.; Asselberghs, I.; Clays, K.; Brunschwig, B. S.; Harris, J. A.; Garin, J.; Orduna, J. “Pentacyanoiron(II) as an Electron Donor Group for Nonlinear Optics: Medium-Responsive Properties and Comparisons with Related Pentaammineruthenium(II) Complexes.” JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 2006, 128 (37), 12192–12204; https://doi.org/10.1021/ja063449m.

138.     Coe, B. J.; Harries, J. L.; Harris, J. A.; Brunschwig, B. S.; Horton, P. N.; Hursthouse, M. B. “Extended Dipolar Nonlinear Optical Chromophores Based on Trans-Bis[1,2-Phenylenebis(Dimethylarsine)]Chlororuthenium(II) Centers.” INORGANIC CHEMISTRY 2006, 45 (26), 11019–11029; https://doi.org/10.1021/ic061659u.

139.     Coe, B. J.; Harries, J. L.; Helliwell, M.; Brunschwig, B. S.; Harris, J. A.; Asselberghs, I.; Hung, S. T.; Clays, K.; Horton, P. N.; Hursthouse, M. B. “Syntheses and Quadratic Optical Nonlinearities of Ruthenium(II) Complexes with Ethynyl-Connected N-Methylpyridinium Electron Acceptors.” Inorganic Chemistry 2006, 45 (3), 1215–1227.

140.     Webb, L. J.; Nemanick, E. J.; Biteen, J. S.; Knapp, D. W.; Michalak, D. J.; Traub, M. C.; Chan, A. S. Y.; Brunschwig, B. S.; Lewis, N. S. “High-Resolution X-Ray Photoelectron Spectroscopic Studies of Alkylated Silicon(111) Surfaces.” Journal of Physical Chemistry B 2005, 109 (9), 3930–3937.

141.     Hu, X. L.; Cossairt, B. M.; Brunschwig, B. S.; Lewis, N. S.; Peters, J. C. “Electrocatalytic Hydrogen Evolution by Cobalt Difluoroboryl-Diglyoximate Complexes.” Chemical communications 2005, No. 37, 4723–4725; https://doi.org/10.1039/b509188h.

142.     Hamann, T. W.; Gstrein, F.; Brunschwig, B. S.; Lewis, N. S. “Measurement of the Free-Energy Dependence of Interfacial Charge-Transfer Rate Constants Using ZnO/H2O Semiconductor/Liquid Contacts.” Journal of the American Chemical Society 2005, 127 (21), 7815–7824.

143.     Hamann, T. W.; Gstrein, F.; Brunschwig, B. S.; Lewis, N. S. “Measurement of the Dependence of Interfacial Charge-Transfer Rate Constants on the Reorganization Energy of Redox Species at n-ZnO/H<sb>2</sub>O Interfaces.” Journal of the American Chemical Society 2005, 127 (40), 13949–13954.

144.     Creutz, C.; Brunschwig, B. S.; Sutin, N. “Interfacial Charge-Transfer Absorption: Semiclassical Treatment.” Journal of Physical Chemistry B 2005, 109 (20), 10251–10260.

145.     Coe, B. J.; Harris, J. A.; Jones, L. A.; Brunschwig, B. S.; Song, K.; Clays, K.; Garin, J.; Orduna, J.; Coles, S. J.; Hursthouse, M. B. “Syntheses and Properties of Two-Dimensional Charged Nonlinear Optical Chromophores Incorporating Redox-Switchable Cis-Tetraammineruthenium(II) Centers.” Journal of the American Chemical Society 2005, 127 (13), 4845–4859.

146.     Coe, B. J.; Harris, J. A.; Brunschwig, B. S.; Asselberghs, I.; Clays, K.; Garin, J.; Orduna, J. “Three-Dimensional Nonlinear Optical Chromophores Based on Metal-to-Ligand Charge-Transfer from Ruthenium(II) or Iron(II) Centers.” Journal of the American Chemical Society 2005, 127 (38), 13399–13410.

147.     Coe, B. J.; Harris, J. A.; Brunschwig, B. S.; Garin, J.; Orduna, J. “Molecular Salts with Diquat-Based Electron Acceptors for Nonlinear Optics.” Journal of the American Chemical Society 2005, 127 (10), 3284–3285.

148.     Coe, B. J.; Hall, J. J.; Harris, J. A.; Brunschwig, B. S.; Coles, S. J.; Hursthouse, M. B. “Trans-4-[(4-Dimethylaminophenyl)Ethenyl]-N-Methylquinolinium p-Toluenesulfonate Monohydrate.” Acta Crystallographica Section E-Structure Reports Online 2005, 61, O464–O467.

149.     Sutin, N.; Brunschwig, B. S.; Creutz, C.; Feldberg, S. W. “Implications of an Electron-Hopping Model for Charge Transport through Donor-Bridge-Acceptor Assemblies Connected to Metal Electrodes.” J Phys Chem B 2004, 108 (32), 12092–12102; https://doi.org/10.1021/Jp048133k.

150.     Kilsa, K.; Mayo, E. I.; Brunschwig, B. S.; Gray, H. B.; Lewis, N. S.; Winkler, J. R. “Anchoring Group and Auxiliary Ligand Effects on the Binding of Ruthenium Complexes to Nanocrystalline TiO2 Photoelectrodes.” J Phys Chem B 2004, 108 (40), 15640–15651; https://doi.org/10.1021/Jp0369995.

151.     Fujita, E.; Hayashi, Y.; Kita, S.; Brunschwig, B. S. “Spectroscopic Characterization of Intermediates in CO2 Reduction with Rhenium Photocatalysts.” Stud Surf Sci Catal 2004, 153, 271–276.

152.     Coe, B. J.; Jones, L. A.; Harris, J. A.; Brunschwig, B. S.; Asselberghs, I.; Clays, K.; Persoons, A.; Garin, J.; Orduna, J. “Syntheses and Spectroscopic and Quadratic Nonlinear Optical Properties of Extended Dipolar Complexes with Ruthenium(II) Ammine Electron Donor and N-Methylpyridinium Acceptor Groups.” Journal of the American Chemical Society 2004, 126 (12), 3880–3891.

153.     Coe, B. J.; Harris, J. A.; Brunschwig, B. S.; Garin, J.; Orduna, J.; Coles, S. J.; Hursthouse, M. B. “Contrasting Linear and Quadratic Nonlinear Optical Behavior of Dipolar Pyridinium Chromophores with 4-(Dimethylamino)Phenyl or Ruthenium(II) Ammine Electron Donor Groups.” Journal of the American Chemical Society 2004, 126 (33), 10418–10427.

154.     Coe, B. J.; Harries, J. L.; Harris, J. A.; Brunschwig, B. S.; Coles, S. J.; Light, M. E.; Hursthouse, M. B. “Syntheses, Spectroscopic and Molecular Quadratic Nonlinear Optical Properties of Dipolar Ruthenium(II) Complexes of the Ligand 1,2-Phenylenebis(Dimethylarsine).” Dalton transactions 2004, No. 18, 2935–2942; https://doi.org/10.1039/B409432H.

155.     Sutin, N.; Brunschwig, B. S.; Creutz, C. “Using the Marcus Inverted Region for Rectification in Donor-Bridge-Acceptor ‘Wire’ Assemblies.” Journal of Physical Chemistry B 2003, 107 (39), 10687–10690; https://doi.org/10.1021/jp035542s.

156.     Khoudiakov, M.; Parise, A. R.; Brunschwig, B. S. “Interfacial Electron Transfer in Fe(II)(CN)6 4--Sensitized TiO2 Nanoparticles: A Study of Direct Charge Injection by Electroabsorption Spectroscopy.” Journal of the American Chemical Society 2003, 125 (15), 4637–4642.

157.     Hayashi, Y.; Kita, S.; Brunschwig, B. S.; Fujita, E. “Involvement of a Binuclear Species with the Re-C(O)O-Re Moiety in CO<Sub>2</Sub> Reduction Catalyzed by Tricarbonyl Rhenium(I) Complexes with Diimine Ligands: Strikingly Slow Formation of the Re-Re and Re-C(O)O-Re Species from Re(Dmb)(CO)<Sub>3</Sub>S (Dmb ) 4,4’-Dimethyl-2,2’-Bipyridine, S ) Solvent).” Journal of the American Chemical Society 2003, 125 (39), 11976–11987.

158.     Harris, J. A.; Coe, B. J.; Jones, L. A.; Brunschwig, B. S.; Asselberghs, I.; Clays, K.; Persoons, A. Quadratic Nonlinear Optical Properties of Transition Metal Quaterpyridyl Complexes. In Linear and Nonlinear Optics of Organic Materials Iii, Proceedings of the Society of Photo-Optical Instrumentation Engineers (Spie), 2003.

159.     Harries, J. L.; Coe, B. J.; Harris, J. A.; Brunschwig, B. S. Molecular Quadratic Nonlinear Optical Properties of Dipolar Ruthenium(II) Arsine Complexes. In Linear and Nonlinear Optics of Organic Materials Iii, Kuzyk, M. G.; Eich, M.; Norwood, R. A., Eds., Proceedings of the Society of Photo-Optical Instrumentation Engineers (Spie), 2003; https://doi.org/10.1117/12.507840.

160.     Coe, B. J.; Jones, L. A.; Harris, J. A.; Asselberghs, I.; Wostyn, K.; Clays, K.; Persoons, A.; Brunschwig, B. S.; Garin, J.; Orduna, J. Quadratic Nonlinear Optical Properties of Novel Pyridinium Salts. In Linear and Nonlinear Optics of Organic Materials Iii, Kuzyk, M. G.; Eich, M.; Norwood, R. A., Eds., Proceedings of the Society of Photo-Optical Instrumentation Engineers (Spie), 2003; https://doi.org/10.1117/12.506832.

161.     Coe, B. J.; Jones, L. A.; Harris, J. A.; Sanderson, E. E.; Brunschwig, B. S.; Asselberghs, I.; Clays, K.; Persoons, A. “Molecular Quadratic Non-Linear Optical Properties of Dipolar Trans-Tetraammineruthenium(II) Complexes with Pyridinium and Thiocyanate Ligands.” Dalton Transactions 2003, No. 11, 2335–2341; https://doi.org/10.1039/b302668j.

162.     Coe, B. J.; Jones, L. A.; Harris, J. A.; Brunschwig, B. S.; Asselberghs, I.; Clays, K.; Persoons, A. “Highly Unusual Effects of Ð-Conjugation Extension on the Molecular Linear and Quadratic Nonlinear Optical Properties of Ruthenium(II) Ammine Complexes.” Journal of the American Chemical Society 2003, 125 (4), 862–863.

163.     Coe, B. J.; Harris, J. A.; Brunschwig, B. S. “Determination of the Molecular Quadratic Non-Linear Optical Responses of V-Shaped Metallochromophores by Using Stark Spectroscopy.” Dalton Transactions 2003, No. 12, 2384–2386; https://doi.org/10.1039/b304085b.

164.     Coe, B. J.; Harris, J. A.; Asselberghs, I.; Wostyn, K.; Clays, K.; Persoons, A.; Brunschwig, B. S.; Coles, S. J.; Gelbrich, T.; Light, M. E.; et al. “Quadratic Optical Nonlinearities of N-Methyl and N-Aryl Pyridinium Salts.” Advanced Functional Materials 2003, 13 (5), 347–357; https://doi.org/10.1002/adfm200300026.

165.     Coe, B. J.; Harris, J. A.; Brunschwig, B. S. “Electroabsorption Spectroscopic Studies of Dipolar Ruthenium(II) Complexes Possessing Large Quadratic Nonlinear Optical Responses.” Journal of Physical Chemistry A 2002, 106 (6), 897–905; https://doi.org/10.1021/jp012320q.

166.     Brunschwig, B. S.; Creutz, C.; Sutin, N. “Optical Transitions of Symmetrical Mixed-Valence Systems in the Class II–III Transition Regime.” Chemical Society Reviews 2002, 31 (3), 168–184; https://doi.org/10.1039/b008034i.

167.     Thompson, D. W.; Wishart, J. F.; Brunschwig, B. S.; Sutin, N. “Efficient Generation of the Ligand Field Excited State of Tris-(2,2’-Bipyridine)-Ruthenium(II) through Sequential Two-Photon Capture by [Ru(Bpy)<Sub>3</Sub>]2+ or Electron Capture by [Ru(Bpy)<Sub>3</Sub>]3+.” Journal of Physical Chemistry A 2001, 105 (35), 8117–8122; https://doi.org/10.1021/jp011854o.

168.     Coe, B. J.; Harris, J. A.; Clays, K.; Persoons, A.; Wostyn, K.; Brunschwig, B. S. “A Comparison of the Pentaammine(Pyridyl)Ruthenium(II) and 4-(Dimethylamino)Phenyl Groups as Electron Donors for Quadratic Non-Linear Optics.” Chemical Communications 2001, No. 17, 1548–1549; https://doi.org/10.1039/b103543f.

169.     Grodkowski, J.; Dhanasekaran, T.; Neta, P.; Hambright, P.; Brunschwig, B. S.; Shinozaki, K.; Fujita, E. “Reduction of Cobalt and Iron Phthalocyanines and the Role of the Reduced Species in Catalyzed Photoreduction of CO2.” Journal of Physical Chemistry A 2000, 104 (48), 11332–11339; https://doi.org/10.1021/jp002709y.

170.     Hamada, T.; Brunschwig, B. S.; Eifuku, K.; Fujita, E.; Korner, M.; Sakaki, S.; van Eldik, R.; Wishart, J. F. “Enantioselectivities in Electron-Transfer and Excited State Quenching Reactions of a Chiral Ruthenium Complex Possessing a Helical Structure.” Journal of Physical Chemistry A 1999, 103 (29), 5645–5654; https://doi.org/10.1021/jp991116o.

171.     Brunschwig, B. S.; Sutin, N. “Energy Surfaces, Reorganization Energies, and Coupling Elements in Electron Transfer*.” Coordination Chemistry Reviews 1999, 187, 233–254; https://doi.org/10.1016/s0010-8545(98)00255-0.

172.     Yan, S. G.; Brunschwig, B. S.; Creutz, C.; Fujita, E.; Sutin, N. “Reversible Formation of Bis(2,2’-Bipyridine)Rhodium(III) Dihydride from Bis(2,2’-Bipyridine)Rhodium(I) and Dihydrogen. Direct Transfer of Dihydrogen from Rhodium(III) Dihydride to Rhodium(I).” Journal of the American Chemical Society 1998, 120 (40), 10553–10554; https://doi.org/10.1021/ja982208e.

173.     Hamada, T.; Sakaki, S.; Brunschwig, B. S.; Fujita, E.; Wishart, J. F. “High Enantioselectivity in the Electron Transfer Reaction between a Ru(II) Complex of Menbpy Anion Radical, Ru(Menbpy)3)<SUP>+</SUP> [Menbpy = 4,4 ’-Di{(1R,2S,5R)-(-)-Menthoxycarbonyl}-2,2 ’-Bipyridine] and [Co(Acac)3] : A Pulse Radiolysis Study.” Chemistry Letters 1998, No. 12, 1259–1260; https://doi.org/10.1246/cl.1998.1259.

174.     Fujita, E.; Brunschwig, B. S.; Cabelli, D.; Renner, M. W.; Furenlid, L. R.; Ogata, T.; Wada, Y.; Yanagida, S. Photochemical Carbon Dioxide Reduction with Metal Complexes: Differences between Cobalt and Nickel Macrocycles. In Advances in Chemical Conversions for Mitigating Carbon Dioxide, Inui, T.; Anpo, M.; Izui, K.; Yanagida, S.; Yamaguchi, T., Eds., Studies in Surface Science and Catalysis, 1998.

175.     Cheng, T. Y.; Brunschwig, B. S.; Bullock, R. M. “Hydride Transfer Reactions of Transition Metal Hydrides: Kinetic Hydricity of Metal Carbonyl Hydrides.” Journal of the American Chemical Society 1998, 120 (50), 13121–13137; https://doi.org/10.1021/ja9820036.

176.     Brunschwig, B. S.; Creutz, C.; Sutin, N. “Electroabsorption Spectroscopy of Charge Transfer States of Transition Metal Complexes.” Coordination Chemistry Reviews 1998, 177, 61–79; https://doi.org/10.1016/s0010-8545(98)00188-x.

177.     Shin, Y. K.; Szalda, D. J.; Brunschwig, B. S.; Creutz, C.; Sutin, N. “Electronic and Molecular Structures of Pentaammineruthenium Pyridine and Benzonitrile Complexes as a Function of Oxidation State.” Inorganic Chemistry 1997, 36 (14), 3190–3197; https://doi.org/10.1021/ic9700967.

178.     Shin, Y. K.; Brunschwig, B. S.; Creutz, C.; Sutin, N. “Electroabsorption Spectroscopy of Charge-Transfer States of Transition-Metal Complexes. 2. Metal-to-Ligand and Ligand-to-Metal Charge-Transfer Excited States of Pentaammineruthenium Complexes.” Journal of Physical Chemistry 1996, 100 (20), 8157–8169; https://doi.org/10.1021/jp953395v.

179.     Shin, Y. G. K.; Brunschwig, B. S.; Creutz, C.; Newton, M. D.; Sutin, N. “Orbital Analysis of Metal-to-Ligand Charge Transfer and Oxidation in (NH3)5RuL2+ Complexes: Effective t2g Orbital Ordering and the Role of Ligand π and Π* Orbitals.” Journal of Physical Chemistry 1996, 100 (4), 1104–1110; https://doi.org/10.1021/jp9517817.

180.     Shin, Y. G. K.; Brunschwig, B. S.; Creutz, C.; Sutin, N. “Toward a Quantitative Understanding of Dipole-Moment Changes in Charge-Transfer Transitions: Electroabsorption Spectroscopy of Transition-Metal Complexes.” Journal of the American Chemical Society 1995, 117 (33), 8668–8669; https://doi.org/10.1021/ja00138a024.

181.     Ogata, T.; Yanagida, S.; Brunschwig, B. S.; Fujita, E. “Mechanistic and Kinetic-Studies of Cobalt Macrocycles in a Photochemical, CO<Sub>2</Sub>2 Reduction System.” Energy Conversion and Management 1995, 36 (6–9), 669–672.

182.     Ogata, T.; Yanagida, S.; Brunschwig, B. S.; Fujita, E. “Mechanistic and Kinetic Studies of Cobalt Macrocycles in a Photochemical C02 Reduction System: Evidence of Co-C02 Adducts as Intermediates.” Journal of the American Chemical Society 1995, 117 (25), 6708–6716; https://doi.org/10.1021/ja00130a009.

183.     Fujita, E.; Brunschwig, B. S.; Ogata, T.; Yanagida, S. “Toward Photochemical Carbon Dioxide Activation by Transition Metal Complexes.” Coordination Chemistry Reviews 1994, 132, 195–200; https://doi.org/10.1016/0010-8545(94)80040-5.

184.     Sahni, S. K.; Drew, M. G. B.; Bell, T. W.; Brunschwig, B. S. “Building Blocks for Polymetallic Ruthenium(II) and Osmium(II) Polypyridine Luminnophores.” Journal of the Chemical Society-Chemical Communications 1993, No. 2, 123–125; https://doi.org/10.1039/c39930000123.

185.     Fujita, E.; Creutz, C.; Sutin, N.; Brunschwig, B. S. “Carbon Dioxide Activation by Cobalt Macrocycles: Evidence of Hydrogen Bonding between Bound CO2 and the Macrocycle in Solution.” Inorganic Chemistry 1993, 32 (12), 2657–2662; https://doi.org/10.1021/ic00064a015.

186.     Milder, S. J.; Brunschwig, B. S. “Factors Affecting Nonradlative Decay: Temperature Dependence of the Picosecond Fluorescence Lifetime of Pt<Sub>2</Sub>( Pop)<Sub>4</Sub>4-,".” Journal of Physical Chemistry 1992, 96 (5), 2189–2196; https://doi.org/10.1021/j100184a030.

187.     Fujita, E.; Milder, S. J.; Brunschwig, B. S. “Photophysical Properties of Covalently Attached Ru(Bpy)<sub>3</Sub<sup2+</sup> and Mcyclam2M (M = NI, H,Sub>2</sub>) Complexes.” Inorganic Chemistry 1992, 31 (11), 2079–2085; https://doi.org/10.1021/ic00037a019.

188.     Chou, M. H.; Brunschwig, B. S.; Creutz, C.; Sutin, N.; Yeh, A.; Chang, R. C.; Lin, C. T. “Facile Amido to Pyridyl Isomerization: Pentaammineruthenium(II) Walks the Nicotinamide and Isonicotinamide Rings.” Inorganic Chemistry 1992, 31 (26), 5347–5348; https://doi.org/10.1021/ic00052a003.

189.     Sutin, N.; Brunschwig, B. S. “Some Aspects of Electron-Transfer in Biological-Systems.” Advances in Chemistry Series 1990, No. 226, 65–88.

190.     Sutin, N.; Brunschwig, B. S. Some Aspects of Electron-Transfer in Biological-Systems. In Electron Transfer in Biology and the Solid State: Inorganic Compounds with Unusual Properties, Advances in Chemistry Series, 1990.

191.     Brunschwig, B. S.; Sutin, N. “Directional Electron Transfer: Conformational Interconversions and Their Effects on Observed Electron-Transfer Rate Constants.” Journal of the American Chemical Society 1989, 111 (19), 7454–7465; https://doi.org/10.1021/ja00201a028.

192.     Sutin, N.; Brunschwig, B. S.; Creutz, C.; Winkler, J. R. “Nuclear Reorganization Barriers to Electron-Transfer.” Pure and Applied Chemistry 1988, 60 (12), 1817–1830; https://doi.org/10.1351/pac198860121817.

193.     Brunschwig, B. S.; Sutin, N. “Rate-Constant Expression for Nonadiabatic Electron-Transfer Reactions.” Comments Inorg. Chem. 1987, 6 (4), 209–235.

194.     Brunschwig, B. S.; Ehrenson, S.; Sutin, N. “Solvent Reorganization in Optical and Thermal. Electron-Transfer Processes: Solvatochromism and Intramolecular Electron-Transfer Barriers in Spheroidal Molecules.” Journal of Physical Chemistry 1987, 91 (18), 4714–4723; https://doi.org/10.1021/j100302a017.

195.     Liu, D. K.; Brunschwig, B. S.; Creutz, C.; Sutin, N. “Formation of Electronically Excited Products in Electron-Transfer Reactions: Reaction of Polypyridine Complexes of Cobalt(I) and Ruthenium(III) in Acetonitrile.” Journal of the American Chemical Society 1986, 108 (8), 1749–1755; https://doi.org/10.1021/ja00268a006.

196.     Brunschwig, B. S.; Ehrenson, S.; Sutin, N. “Solvent Reorganization in Optical and Thermal Electron-Transfer Processes.” Journal of Physical Chemistry 1986, 90 (16), 3657–3668; https://doi.org/10.1021/j100407a037.

197.     Krishnan, C. V.; Brunschwig, B. S.; Creutz, C.; Sutin, N. “Homogeneous Catalysis of the Photoreduction of Water. 6. Mediation by Polypyridine Complexes of Ruthenium(II) and Cobalt(II) in Alkaline Media.” Journal of the American Chemical Society 1985, 107 (7), 2005–2015; https://doi.org/10.1021/ja00293a035.

198.     Brunschwig, B. S.; Delaive, P. J.; English, A. M.; Goldberg, M.; Mayo, S. L.; Sutin, N.; Gray, H. B. “Kinetics and Mechanisms of Electron Transfer between Blue Copper Proteins and Electronically Excited Chromium and Ruthenium Polypyridine Complexes.” Inorganic Chemistry 1985, 24 (23), 3743–3749; https://doi.org/10.1021/ic00217a010.

199.     Ghosh, P. K.; Brunschwig, B. S.; Chou, M.; Creutz, C.; Sutin, N. “Thermal and Light-Induced Reduction of Ru( Bpy )<SUB>3</SUB<SUP>3+</SUP> Aqueous Solution.” Journal of the American Chemical Society 1984, 106 (17), 4772–4783; https://doi.org/10.1021/ja00329a022.

200.     Brunschwig, B. S.; Ehrenson, S.; Sutin, N. “Distance Dependence of Electron-Transfer Reactions: Rate Maxima and Rapid Rates at Large Reactant Separations.” Journal of the American Chemical Society 1984, 106 (22), 6858–6859; https://doi.org/10.1021/ja00334a074.

201.     Smalley, J. F.; Feldberg, S. W.; Brunschwig, B. S. “Mechanism of Porphyrin Ion Production from the Triplet State of Magnesium Octaethylporphyrin.” Journal of Physical Chemistry 1983, 87 (10), 1757–1765; https://doi.org/10.1021/j100233a022.

202.     Brunschwig, B. S.; Chou, M. H.; Creutz, C.; Ghosh, P.; Sutin, N. “Mechanisms of Water Oxidation to Oxygen: Cobalt(IV) as an Intermediate in the Aquocobalt(II)Xatalyzed Reaction.” Journal of the American Chemical Society 1983, 105 (14), 4832–4833; https://doi.org/10.1021/ja00352a050.

203.     Sutin, N.; Brunschwig, B. S. “Electron-Transfer in Weakly Interacting Systems.” Acs Symposium Series 1982, 198, 105–135.

204.     Brunschwig, B. S.; Creutz, C.; Macartney, D. H.; Sham, T. K.; Sutin, N. “The Role of Inner-Sphere Configuration Changes in Electron-Exchange Reactions of Metal Complexes.” Faraday Discussions 1982, 74, 113–127; https://doi.org/10.1039/dc9827400113.

205.     Sham, T. K.; Brunschwig, B. S. “X-Ray Absorption Spectra of Mn04- and Mn042- with Synchrotron Radiation: A Study of Structure and Bonding Properties of Transition-Metal Complexes in Solution.” Journal of the American Chemical Society 1981, 103 (6), 1590–1591; https://doi.org/10.1021/ja00396a063.

206.     Malin, J. M.; Brunschwig, B. S.; Brown, G. M.; Kwan, K. S. “Laser-Flash-Induced Dissociation and Recombination of Aqueous Pentacyano(2-Methylpyrazine)Ferrate(II) Ion.” Inorganic Chemistry 1981, 20 (5), 1438–1441; https://doi.org/10.1021/ic50219a022.

207.     Brunschwig, B. S.; Sutin, N. “Visible-Light Photolysis of Tris(Bipyridine)Ruthenium(II)-Titanium(III) Solutions.” Chemical Physics Letters 1981, 77 (1), 63–65; https://doi.org/10.1016/0009-2614(81)85600-x.

208.     Bergkamp, M. A.; Brunschwig, B. S.; Gutlich, P.; Netzel, T. L.; Sutin, N. “Temperature-Dependence of the Lifetimes of the Ligand-Field States of Tris(1,10-Phenanthroline)Iron(II).” Chemical Physics Letters 1981, 81 (1), 147–150; https://doi.org/10.1016/0009-2614(81)85346-8.

209.     Brunschwig, B. S.; Logan, J.; Newton, M. D.; Sutin, N. “A Semiclassical Treatment of Electron-Exchange Reactions. Application to the Hexaaquoiron(II)-Hexaaquoiron( III) System.” Journal of the American Chemical Society 1980, 102 (18), 5798–5809; https://doi.org/10.1021/ja00538a017.

210.     Creutz, C.; Sutin, N.; Brunschwig, B. S. “Excited-State Photochemistry in the Tris(2,2’-Bipyridine)Ruthenium(II)-Sulfite System.” Journal of the American Chemical Society 1979, 101 (5), 1297–1298; https://doi.org/10.1021/ja00499a050.

211.     Brunschwig, B. S.; Sutin, N. “Titanium(III) Chemistry: Electron-Transfer Reactions with Ground-State Poly( Pyridine)Osmium( III) Complexes, Quenching Reactions with Excited-State Poly( Pyridine)Ruthenium(II) Complexes, and Formal Reduction Potentials.” Inorganic Chemistry 1979, 18 (7), 1731–1736; https://doi.org/10.1021/ic50197a002.

212.     Brown, G. M.; Brunschwig, B. S.; Creutz, C.; Endicott, J. F.; Sutin, N. “Homogeneous Catalysis of the Photoreduction of Water by Visible Light. Mediation by a Tris(2,2‘-Bipyridine)Ruthenium(II)-Cobalt(II) Macrocycle System.” Journal of the American Chemical Society 1979, 101 (5), 1298–1300; https://doi.org/10.1021/ja00499a051.

213.     Brunschwig, B. S.; Sutin, N. “Kinetics and Mechanism of the Oxidation of Horse Heart Ferrocytochrome c by Tris(1,10-Phenanthroline)Cobalt(III) at Low PH.” Inorganic Chemistry 1976, 15 (3), 631–634; https://doi.org/10.1021/ic50157a026.