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Bruce S. Brunschwig

Recent Publications

  1. Coe, B. J., Foxon, S. P., Pilkington, R. A., Sanchez, S., Whittaker, D., Clays, K., Depotter, G., and Brunschwig, B. S. Nonlinear Optical Chromophores with Two Ferrocenyl, Octamethylferrocenyl, or 4-(Diphenylamino)phenyl Groups Attached to Rhenium(I) or Zinc(II) Centers. Organometallics 2015 34, (9) 1701-15. 10.1021/acs.organomet.5600193I.

  2. Lichterman, M. F., Hu, S., Richter, M. H., Crumlin, E. J., Axnanda, S., Favaro, M., Drisdell, W., Hussain, Z., Mayer, T., Brunschwig, B. S., Lewis, N. S., Liu, Z., and Lewerenz, H.-J. Direct observation of the energetics at a semiconductor/liquid junction by operando X-ray photoelectron spectroscopy. Energy Envir. Sci. 2015 8, (8) 2409-16. 10.1039/c5ee01014dI.

  3. Liu, R., Han, L., Huang, Z., Ferrer, I. M., Smets, A. H. M., Zeman, M., Brunschwig, B. S., and Lewis, N. S. A low-temperature synthesis of electrochemical active Pt nanoparticles and thin films by atomic layer deposition on Si(111) and glassy carbon surfaces. Thin Solid Films 2015 586, 28-34. 10.1016/j.tsf.2015.04.018I.

  4. McDowell, M. T., Lichterman, M. F., Carim, A. I., Liu, R., Hu, S., Brunschwig, B. S., and Lewis, N. S. The Influence of Structure and Processing on the Behavior of TiO2 Protective Layers for Stabilization of n-Si/TiO2/Ni Photoanodes for Water Oxidation. ACS Applied Materials & Interfaces 2015 7, (28) 15189-99. 10.1021/acsami.5b00379I.

  5. O'Leary, L. E., Strandwitz, N. C., Roske, C. W., Pyo, S., Brunschwig, B. S., and Lewis, N. S. Use of Mixed CH3-/HC(O)CH2CH2-Si(111) Functionality to Control Interfacial Chemical and Electronic Properties During the Atomic-Layer Deposition of Ultrathin Oxides on Si(111). J. Phys. Chem. Lett. 2015 6, (4) 722-26. 10.1021/jz502542aI.

  6. Plymale, N. T., Kim, Y.-G., Soriaga, M. P., Brunschwig, B. S., and Lewis, N. S. Synthesis, Characterization, and Reactivity of Ethynyl- and Propynyl-Terminated Si(111) Surfaces. J. Phys. Chem. C 2015 119, (34) 19847-62. 10.1021/acs.jpcc.5b05028I.

  7. Roske, C. W., Popczun, E. J., Seger, B., Read, C. G., Pedersen, T., Hansen, O., Vesborg, P. C. K., Brunschwig, B. S., Schaak, R. E., Chorkendorff, I., Gray, H. B., and Lewis, N. S. Comparison of the Performance of CoP-Coated and Pt-Coated Radial Junction n(+)p-Silicon Microwire-Array Photocathodes for the Sunlight-Driven Reduction of Water to H-2(g). J. Phys. Chem. Lett. 2015 6, (9) 1679-83. 10.1021/acs.jpclett.5b00495I.

  8. Soriaga, M. P., Baricuatro, J. H., Cummins, K. D., Kim, Y.-G., Saadi, F. H., Sun, G., McCrory, C. C. L., McKone, J. R., Velazquez, J. M., Ferrer, I. M., Carim, A. I., Javier, A., Chmielowiec, B., Lacy, D. C., Gregoire, J. M., Sanabria-Chinchilla, J., Amashukeli, X., Royea, W. J., Brunschwig, B. S., Hemminger, J. C., Lewis, N. S., and Stickney, J. L. Electrochemical surface science twenty years later: Expeditions into the electrocatalysis of reactions at the core of artificial photosynthesis. Surf. Sci. 2015 631, 285-94. 10.1016/j.susc.2014.06.028I.

  9. Sun, K., Kuang, Y., Verlage, E., Brunschwig, B. S., Tu, C. W., and Lewis, N. S. Sputtered NiOx Films for Stabilization of p(+)n-InP Photoanodes for Solar-Driven Water Oxidation. Advanced Energy Materials 2015 5, (11). 10.1002/aenm.201402276I.

  10. Sun, K., McDowell, M. T., Nielander, A. C., Hu, S., Shaner, M. R., Yang, F., Brunschwig, B. S., and Lewis, N. S. Stable Solar-Driven Water Oxidation to O-2(g) by Ni-Oxide-Coated Silicon Photoanodes. J. Phys. Chem. Lett. 2015 6, (4) 592-98. 10.1021/jz5026195I.

  11. Sun, K., Saadi, F. H., Lichterman, M. F., Hale, W. G., Wang, H.-P., Zhou, X., Plymale, N. T., Omelchenko, S. T., He, J.-H., Papadantonakis, K. M., Brunschwig, B. S., and Lewis, N. S. Stable solar-driven oxidation of water by semiconducting photoanodes protected by transparent catalytic nickel oxide films. Proc. Natl. Acad. Sci. USA 2015 112, (12) 3612-17. 10.1073/pnas.1423034112I.

  12. Wong, K. T., Kim, Y.-G., Soriaga, M. P., Brunschwig, B. S., and Lewis, N. S. Synthesis and Characterization of Atomically Flat Methyl-Terminated Ge(111) Surfaces. J. Am. Chem. Soc. 2015 137, (28) 9006-14. 10.1021/jacs.5b03339I.
  13. Blakemore, J. D., Hernandez, E. S., Sattler, W., Hunter, B. M., Henling, L. M., Brunschwig, B. S., and Gray, H. B. Pentamethylcyclopentadienyl rhodium complexes. Polyhedron 2014 84, 14-18. 10.1016/j.poly.2014.05.022I.

  14. Coe, B. J., Helliwell, M., Peers, M. K., Raftery, J., Rusanova, D., Clays, K., Depotter, G., and Brunschwig, B. S. Synthesis, Structures, and Optical Properties of Ruthenium(II) Complexes of the Tris(1-pyrazolyl)methane Ligand. Inorg. Chem. 2014 53, (7) 3798-811

  15. Coridan, R. H., Arpin, K. A., Brunschwig, B. S., Braun, P. V., and Lewis, N. S. Photoelectrochemical Behavior of Hierarchically Structured Si/WO3 Core-Shell Tandem Photoanodes. Nano Lett. 2014 14, (5) 2310-17

  16. Hu, S., Shaner, M. R., Beardslee, J. A., Lichterman, M., Brunschwig, B. S., and Lewis, N. S. Amorphous TiO2 coatings stabilize Si, GaAs, and GaP photoanodes for efficient water oxidation. Science 2014 344, (6187) 1005-09

  17. Huang, Z. Q., McKone, J. R., Xiang, C. X., Grimm, R. L., Warren, E. L., Spurgeon, J. M., Lewerenz, H. J., Brunschwig, B. S., and Lewis, N. S. Comparison between the measured and modeled hydrogen-evolution activity of Ni- or Pt-coated silicon photocathodes. Int. J. Hydrogen Energy 2014 39, (28) 16220-26. 10.1016/j.ijhydene.2013.12.162I.

  18. Laga, S. M., Blakemore, J. D., Henling, L. M., Brunschwig, B. S., and Gray, H. B. Catalysis of Proton Reduction by a BO4 -Bridged Dicobalt Glyoxime. Inorg. Chem. 2014 53, (24) 12668-70. 10.1021/ic501804hI.

  19. Lattimer, J. R. C., Blakemore, J. D., Sattler, W., Gul, S., Chatterjee, R., Yachandra, V. K., Yano, J., Brunschwig, B. S., Lewis, N. S., and Gray, H. B. Assembly, characterization, and electrochemical properties of immobilized metal bipyridyl complexes on silicon(111) surfaces. Dalton Transactions 2014 43, (40) 15004-12. 10.1039/c4dt01149jI.

  20. Lichterman, M. F., Carim, A. I., McDowell, M. T., Hu, S., Gray, H. B., Brunschwig, B. S., and Lewis, N. S. Stabilization of n-cadmium telluride photoanodes for water oxidation to O-2(g) in aqueous alkaline electrolytes using amorphous TiO2 films formed by atomic-layer deposition. Energy Envir. Sci. 2014 7, (10) 3334-37. 10.1039/c4ee01914hI.

  21. McDowell, M. T., Lichterman, M. F., Spurgeon, J. M., Hu, S., Sharp, I. D., Brunschwig, B. S., and Lewis, N. S. Improved Stability of Polycrystalline Bismuth Vanadate Photoanodes by Use of Dual-Layer Thin TiO2/Ni Coatings. J. Phys. Chem. C 2014 118, (34) 19618-24. 10.1021/jp506133yI.

  22. McKone, J. R., Marinescu, S. C., Brunschwig, B. S., Winkler, J. R., and Gray, H. B. Earth-abundant hydrogen evolution electrocatalysts. Chemical Science 2014 5, (3) 865-78. Doi 10.1039/C3sc51711jI.

  23. Santori, E. A., Strandwitz, N. C., Grimm, R. L., Brunschwig, B. S., Atwater, H. A., and Lewis, N. S. Operation of lightly doped Si microwires under high-level injection conditions. Energy Envir. Sci. 2014 7, (7) 2329-38. 10.1039/c4ee00202dI.

  24. Velazquez, J. M., Saadi, F. H., Pieterick, A. P., Spurgeon, J. M., Soriaga, M. P., Brunschwig, B. S., and Lewis, N. S. Synthesis and hydrogen-evolution activity of tungsten selenide thin films deposited on tungsten foils. J. Electroanal. Chem. 2014 716, 45-48. Doi 10.1016/J.Jelechem.2013.11.030I.

  25. Blakemore, J. D., Gupta, A., Warren, J. J., Brunschwig, B. S., and Gray, H. B.Noncovalent Immobilization of Electrocatalysts on Carbon Electrodes for Fuel Production. J. Am. Chem. Soc. 2013 135, (49) 18288-91

  26. Coe, B. J., Foxon, S. P., Helliwell, M., Rusanova, D., Brunschwig, B. S., Clays, K., Depotter, G., Nyk, M., Samoc, M., Wawrzynczyk, D., Garin, J., and Orduna, J. Heptametallic, octupolar nonlinear optical chromophores with six ferrocenyl substituents. Chemistry 2013 19, (21) 6613-29. 10.1002/chem.201204453I.

  27. Coe, B. J., Foxon, S. P., Helliwell, M., Rusanova, D., Brunschwig, B. S., Clays, K., Depotter, G., Nyk, M., Samoc, M., Wawrzynczyk, D., Garin, J., and Orduna, J. Heptametallic, Octupolar Nonlinear Optical Chromophores with Six Ferrocenyl Substituents. Chem. Eur. J. 2013 19, (21) 6613-29. 10.1002/chem.201204453I.

  28. Coridan, R. H., Shaner, M., Wiggenhorn, C., Brunschwig, B. S., and Lewis, N. S. Electrical and Photoelectrochemical Properties of WO3/Si Tandem Photoelectrodes. J. Phys. Chem. C 2013 117, (14) 6949-57. Doi 10.1021/Jp311947xI.

  29. Dasgupta, S., Brunschwig, B. S., Winkler, J. R., and Gray, H. B. Solar fuels editorial. Chem. Soc. Rev. 2013 42, (6) 2213-14. 10.1039/c3cs90016aI.

  30. Fitch, A., Strandwitz, N. C., Brunschwig, B. S., and Lewis, N. S. A Comparison of the Behavior of Single Crystalline and Nanowire Array ZnO Photoanodes. J. Phys. Chem. C 2013 117, (5) 2008-15. Doi 10.1021/Jp3098457I.

  31. Gleason-Rohrer, D. C., Brunschwig, B. S., and Lewis, N. S. Measurement of the Band Bending and Surface Dipole at Chemically Functionalized Si(111)/Vacuum Interfaces. J. Phys. Chem. C 2013 117, (35) 18031-42. Doi 10.1021/Jp401585sI.

  32. Lattimer, J. R. C., Brunschwig, B. S., Lewis, N. S., and Gray, H. B. Redox Properties of Mixed Methyl/Vinylferrocenyl Monolayers on Si(111) Surfaces. J. Phys. Chem. C 2013 117, (51) 27012-22. Doi 10.1021/Jp409958cI.

  33. Lichterman, M. F., Shaner, M. R., Handler, S. G., Brunschwig, B. S., Gray, H. B., Lewis, N. S., and Spurgeon, J. M. Enhanced Stability and Activity for Water Oxidation in Alkaline Media with Bismuth Vanadate Photoelectrodes Modified with a Cobalt Oxide Catalytic Layer Produced by Atomic Layer Deposition. J. Phys. Chem. Lett. 2013 4, (23) 4188-91. Doi 10.1021/Jz4022415I.

  34. Mi, Q. X., Coridan, R. H., Brunschwig, B. S., Gray, H. B., and Lewis, N. S. Photoelectrochemical oxidation of anions by WO3 in aqueous and nonaqueous electrolytes. Energy Envir. Sci. 2013 6, (9) 2646-53. Doi 10.1039/C3ee40712hI.

  35. O'Leary, L. E., Rose, M. J., Ding, T. X., Johansson, E., Brunschwig, B. S., and Lewis, N. S. Heck coupling of olefins to mixed methyl/thienyl monolayers on Si(111) surfaces. J. Am. Chem. Soc. 2013 135, (27) 10081-90. 10.1021/ja402495eI.

  36. O'Leary, L. E., Rose, M. J., Ding, T. X., Johansson, E., Brunschwig, B. S., and Lewis, N. S. Heck Coupling of Olefins to Mixed Methyl/Thienyl Monolayers on Si(111) Surfaces. J. Am. Chem. Soc. 2013 135, (27) 10081-90. 10.1021/ja402495eI.

  37. Reyes-Gil, K. R., Wiggenhorn, C., Brunschwig, B. S., and Lewis, N. S. Comparison between the Quantum Yields of Compact and Porous WO3 Photoanodes. J. Phys. Chem. C 2013 117, (29) 14947-57. Doi 10.1021/Jp4025624I.

  38. Walter, M. G., Liu, X. L., O'Leary, L. E., Brunschwig, B. S., and Lewis, N. S. Electrical Junction Behavior of Poly(3,4-ethylenedioxythiophene) (PEDOT) Contacts to H-Terminated and CH3-Terminated p-, n-, and n(+)-Si(111) Surfaces. J. Phys. Chem. C 2013 117, (28) 14485-92. 10.1021/jp4018162I.